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Emissions

Mercedes P0420: Catalyst System Efficiency Below Threshold

23 May 2026

By Jamie Armoordon · Mercedes-Benz Trained Technician · TriPoint Diagnostics Ltd
P0420 is stored when the ECU determines that the catalytic converter is not reducing harmful emissions to the required level. On Mercedes diesel vans it is often associated with the oxidation catalyst upstream of the DPF. It is a code that appears straightforward but has several possible causes beyond a failed catalyst.
Multimeter probe testing exhaust temperature sensor reading

What P0420 means

The catalyst efficiency is monitored by comparing exhaust gas composition upstream and downstream of the catalyst using temperature sensors, NOx sensors on equipped models, and the oxygen or lambda sensor where fitted. When the ECU calculates that the conversion efficiency is below threshold, P0420 is stored. This can reflect a genuinely degraded catalyst, a sensor giving incorrect readings, or an upstream fault that is preventing the catalyst from reaching its correct operating temperature.


Common causes on Mercedes diesel vans

A degraded or physically damaged oxidation catalyst is the most direct cause. However P0420 can also be triggered by: a faulty exhaust temperature sensor upstream or downstream of the catalyst giving incorrect efficiency readings, a failed or contaminated NOx sensor on SCR-equipped models creating a false efficiency assessment, an engine fault causing excessive unburned fuel to enter the exhaust and overheat or contaminate the catalyst, and a catalyst that has been physically removed or bypassed. This last cause is identifiable during a diagnostic session and is not something we will advise on or facilitate.

Heavily sooted exhaust sensor removed for inspection

What a diagnostic session looks at

Exhaust temperature sensor plausibility upstream and downstream is checked first. If sensor readings are implausible relative to engine load and conditions, the sensor rather than the catalyst may be at fault. On SCR-equipped models the NOx sensor data is reviewed for correct function. Engine fuelling and combustion health is checked to rule out an upstream fault contributing to catalyst degradation. Physical inspection of the catalyst housing where accessible. If all sensors are plausible and no upstream fault is present, the catalyst itself is the most likely cause.


Related reading

Seeing P0420 on your Mercedes?

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